Separation of palladium and platinum metals by selective …
DOI: 10.1016/j.hydromet.2021.105814 Corpus ID: 245687054; Separation of palladium and platinum metals by selective and simultaneous leaching and extraction with aqueous/non-aqueous solutions

DOI: 10.1016/j.hydromet.2021.105814 Corpus ID: 245687054; Separation of palladium and platinum metals by selective and simultaneous leaching and extraction with aqueous/non-aqueous solutions

The solid leach residue contains 15 to 20 percent platinum-group metals. Sometimes gravity separation is employed prior to flotation; this results in a concentrate containing up to 50 percent platinum metals, making smelting unnecessary. Extraction and refining. The separation chemistry of the platinum-group metals is among the most …

A novel ionic liquid (IL) functionalized with thiodiglycol amic acid containing a soft S donor was synthesized for the effective and efficient extraction of platinum group metals (Ru, Rh, and Pd) from aqueous nitric acid solutions, such as high-level radioactive liquid waste (HLLW). The IL enabled r …

Platinum Group Metals and Compounds View previous versions Hermann Renner, Günther Schlamp, Ingo Kleinwächter, Ernst Drost, Hans Martin Lüschow, Peter Tews, Peter Panster, Manfred Diehl, Jutta Lang, Thomas Kreuzer, Alfons Knödler, Karl Anton Starz, Klaus Dermann, Josef Rothaut, Ralf Drieselmann, Catrin Peter, Rainer …

Section snippets Search method and literature analysis. The literature research was carried out by on the ACS, RSC, ScienceDirect, Google Scholar, and Web of Science database, using key words such as "Platinum group metals", "Precious metals", "separation", "recovery", "extraction", "adsorption", "technology" and so forth.

The solutions resulting from the processing of such materials are characterized by high content of impurities and low content of precious metals. For this reason, in order to obtain pure metals, it is extremely important to choose an effective, selective method for the recovery and separation of the platinum group metals.

Platinum group metals (PGMs), being rare and very valuable, fall into this demand, and the catalytic converters that contain them are recognized as one of the main sources. ... Separation of platinum and rhodium from chloride solutions containing aluminum, magnesium and iron using solvent extraction and precipitation methods. J. …

Mutual separation of platinum group metals (PGMs) is a particularly challenging issue in metal recovery technology. In this study, we report the successful separation of Pt(IV), Pd(II), and Rh(III)...

Solvent Extraction as a Method of Recovery and Separation of Platinum Group Metals. Karolina Pianowska Joanna Kluczka +4 authors K. Leszczyńska-Sejda. Chemistry, Materials Science. Materials. 2023; Platinum group metals (PGMs) are a group of six metals with high market value and key importance to many industrial sectors.

An effective solvent extraction-based method has been developed to recover individual platinum group metals (PGMs) (i.e. Pd, Pt and Rh) with high purity from acidic chloride media using phosphonium-based ionic liquid Cyphos IL 101 ([P 66614] + Cl −) diluted in xylene used as a model of industrial diluents such as SOLVESSO 150.The …

Trends in Sorption Recovery of Platinum Metals: A Critical Survey, Russian Journal of Inorganic Chemistry, 62, 1797-1818 "The most famous and successful technology for the separation of platinum metals, used at some large enterprises around the world, employs the sorbents of the SuperLig® brand produced by IBC Advanced Technologies."

This paper systematically reviews various improvements and new technologies for the separation and purification of PGMs, including solvent extraction, membranes separation, supercritical fluids, solid-phase extraction, photoreduction, and …

Separation of palladium and platinum metals by selective and simultaneous leaching and extraction with aqueous/non-aqueous solutions Hydrometallurgy, Volume 208, 2022, Article 105814 Viet Nhan Hoa Nguyen, …, Man Seung Lee

For this reason, in order to obtain pure metals, it is extremely important to choose an effective, selective method for the recovery and separation of the platinum …

The separation of the individual PGMs, however, has several bottlenecks: (i) slow kinetics, (ii) poor selectivity, (iii) high chemical consumption, and (iv) high waste …

A new technique for selective separation and enrichment of platinum group metals (platinum, palladium, rhodium, iridium, ruthenium) from model hydrochloric and …

1. Introduction. Among platinum-group metals (PGMs), palladium (Pd) and platinum (Pt) are raw elements for the production of advanced materials and automotive exhaust catalysts (Li and Binnemans, 2021; Franc et al., 2005).With highly increasing global demand for PGMs, the recovery of PGMs from secondary resources is …

A Review of the Behaviour of Platinum Group Elements within Natural Magmatic Sulfide Ore Systems. Asymmetric Transfer Hydrogenation in Water with Platinum Group Metal …

The scheme of separation of Pd(II) and Pt(IV) as well as rare platinum metals was proposed for processing technological solutions to obtain individual fractions of precious metals with purity of >99.9%.

To discuss the applicability of a novel macroporous silica-based (MOTDGA–TOA)/SiO2-P adsorbent which was developed to separate platinum group metals (PGMs) from high level liquid waste by extraction chromatography to radiation field, batch adsorption behavior, stability of the adsorbent and retention capability of PGMs …

This chapter deals with the separation of the platinum-group metals from base metal sulfides, and refining of nickel, copper and cobalt and describes the processing routes. Operating details for ...

The content of platinum-group metals is controlled by different analytical methods, which are imposed by high requirements to precision, expression, traceability, and comprehensiveness. ... Separation of platinum and rhodium from chloride solutions containing aluminum, magnesium and iron using solvent extraction and precipitation …

Separation and recovery of some platinum group metals (PGMs) by means of selective photocatalytic reduction by R.J. Kriek, W.J. Engelbrecht, and J.J. Cruywagen * Introduction The economic importance of the platinum group metals (PGMs) for South Africa is …

The separation and purification of the PGM is largely carried out by exploiting differences in the chemistry of their anionic chloro-complexes. These …

A new technique for selective separation and enrichment of platinum group metals (platinum, palladium, rhodium, iridium, ruthenium) from model hydrochloric and chloride media into hydrophobic deep eutectic solvents without the use of chelating agents is presented for the first time.

Extraction and separation of multiple platinum group metals from hydrochloric acid solution with sole 1-hexyl-3-methylimidazole-2-thione using microextraction method. Hydrometallurgy (2017) W. Wei et al. Selective recovery of Au(III), Pt(IV), and Pd(II) from aqueous solutions by liquid–liquid extraction using ionic liquid …

Abstract A novel ionic liquid (IL) functionalized with thiodiglycol amic acid containing a soft S donor was synthesized for the effective and efficient extraction of platinum group metals (Ru, Rh, and Pd) from aqueous nitric acid solutions, such as high-level radioactive liquid waste (HLLW). The IL enabled rapid extraction of Pd(II) with an …

Application of a Novel Phosphonium-Based Ionic Liquid to the Separation of Platinum Group Metals from Automobile Catalyst Leach Liquor. The recovery of platinum group …

Solvent extraction, also known as liquid–liquid extraction, is an effective method for the separation of metals from multi-component solutions. The technique …

In the present article a new and innovative approach for the selective separation of platinum group metals (Pt, Pd, Rh) from Fe-PGM alloys that contain high amounts of silicon (Si) is discussed. The challenge with processing these alloys by conventional hydrometallurgical methods is that the high content of silicon makes the …